index = pd.MultiIndex.from_tuples([('one', 'a'), ('one', 'b'), ('two', 'a'), ('two', 'b')])
>>> s = pd.Series(np.arange(1.0, 5.0), index=index)
>>> s
one a 1.0
b 2.0
two a 3.0
b 4.0
dtype: float64
>>> s.unstack(level=0)
one two
a 1.0 3.0
b 2.0 4.0