day['hour'] = day['date_time'].dt.hour
bussiness_days = day.copy()[day['dayofweek'] <= 4] # 4 == Friday
weekend = day.copy()[day['dayofweek'] >= 5] # 5 == Saturday
by_hour_business = bussiness_days.groupby('hour').mean()
by_hour_weekend = weekend.groupby('hour').mean()
print(by_hour_business['traffic_volume'])
print(by_hour_weekend['traffic_volume'])