SELECT TheKey,
TheData.value('(/Group1/Title/Name)[1]', 'varchar(100)') AS Name,
TheData.value('(/Group1/Title/Phone)[1]', 'varchar(100)') AS Phone,
TheData.value('(/Group1/Title/Email)[1]', 'varchar(250)') AS Email,
TheData.value('(/Group1/Title/State)[1]', 'varchar(100)') AS [State]
FROM MyTable