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dictionary from two columns pandas

pd.Series(df.A.values,index=df.B).to_dict()
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convert 2 columns to dictionary pandas

dict(zip(df.a,df.b))
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dict column to be in multiple columns python

In [2]: df = pd.DataFrame({'a':[1,2,3], 'b':[{'c':1}, {'d':3}, {'c':5, 'd':6}]})

In [3]: df
Out[3]:
   a                   b
0  1           {u'c': 1}
1  2           {u'd': 3}
2  3  {u'c': 5, u'd': 6}

In [4]: df['b'].apply(pd.Series)
Out[4]:
     c    d
0  1.0  NaN
1  NaN  3.0
2  5.0  6.0
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